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NUMERICAL MODELING OF BIOMASS GASIFICATION USING COW DUNG AS FEEDSTOCK

《农业科学与工程前沿（英文）》 2023年 第10卷 第3期   页码 458-467 doi: 10.15302/J-FASE-2023500

摘要：

● Gasification of cow dung was evaluated using Aspen Plus software.

关键词： Aspen Plus     biomass gasification     manure of livestock and poultry     simulation     syngas    

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Hydrogen production by biomass gasification in supercritical or subcritical water with Raney-Ni and other

Aixia PEI, Lisheng ZHANG, Bizheng JIANG, Liejin GUO, Ximin ZHANG, Youjun LV, Hui JIN,

《能源前沿（英文）》 2009年 第3卷 第4期   页码 456-464 doi: 10.1007/s11708-009-0069-y

摘要： Gasification of peanut shell, sawdust and straw in supercritical or subcritical water has been studied in a batch reactor with the presence of a series of Raney-Ni and its mixture with ZnCl or Ca(OH). The main gas products were hydrogen, methane, carbon dioxide, and a small amount of carbon monoxide. Different types of Raney-Ni, containing different metal components such as Fe, Mo or Cr, have different influences on the gasification yield and hydrogen selectivity. The catalysis effect can be improved obviously by adding ZnCl or Ca(OH). Increasing the reaction temperature or adding ZnCl and Ca(OH) could improve the mass of H in gas products and reduce the mass of CH and CO at the same time. The possible mechanism is that ZnCl can decompose the biomass particle by accelerating cellulose hydrolyzation in high-temperature water, increasing more specific surface to admit catalysts, while Ca(OH) can absorb CO to produce CaCO deposit, which can drop out from the reactant system, and which will drive the reaction to get more hydrogen. With respect to the biomass conversion to gas product and selectivity of H at low temperature, the series of Raney-Ni has shown many advantages over other catalysts; thus, this kind of catalyst has great potential to be utilized in the hydrogen industry for the gasification of biomass.

关键词： Different     presence     sawdust     Raney-Ni     Gasification    

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Biomass to dimethyl ether by gasification/synthesis technology

Tiejun WANG, Yuping LI, Longlong MA, Chuangzhi WU

《能源前沿（英文）》 2011年 第5卷 第3期   页码 330-339 doi: 10.1007/s11708-010-0121-y

摘要： Technical and economic analysis was done for the biomass to dimethyl ether (DME) technology to promote the gasification/synthesis route for biofuel production and its application as a fossil fuel substitute. The technology of biomass gasification/synthesis has obvious advantages, including production flexibility, environmental friendliness, economic feasibility, and application versatility. Biomass gasification/synthesis technology integrates bio-DME synthesis, fertilizer production, electricity generation, and waste heat utilization to convert waste biomass residues to DME for use as liquid petroleum gas, transportation fuel substitute, and chemical intermediates, which has been proven to be one of the most effective and clean biomass utilization routes. The 1000 t/a-scale demonstration plant has a bio-DME production rate of 6 to 7 / , biomass gasification efficiency of≥82%, once-through CO conversion of ≥70%, DME selectivity (DME/DME+other organic products) of ≥90%, and a total system efficiency of ≥38%. The demonstration plant also has self-sufficient steam and electricity supply. The 10,000tons/a-scale bio-DME production cost with or without feedstock subsidy is estimated to be 1968 Yuan/t and 2868 Yuan/t, respectively in China. Because of the limitation in biomass feedstock collection cost, massive and disperse commercial plants with a capacity of 10000 t/a bio-DME are more suitable for rural areas.

关键词： technical and economic analysis     biomass     dimethyl ether     gasification/synthesis    

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Catalytic steam reforming of tar for enhancing hydrogen production from biomass gasification: a review

Ru Shien TAN, Tuan Amran TUAN ABDULLAH, Anwar JOHARI, Khairuddin MD ISA

《能源前沿（英文）》 2020年 第14卷 第3期   页码 545-569 doi: 10.1007/s11708-020-0800-2

摘要： Presently, the global search for alternative renewable energy sources is rising due to the depletion of fossil fuel and rising greenhouse gas (GHG) emissions. Among alternatives, hydrogen (H ) produced from biomass gasification is considered a green energy sector, due to its environmentally friendly, sustainable, and renewable characteristics. However, tar formation along with syngas is a severe impediment to biomass conversion efficiency, which results in process-related problems. Typically, tar consists of various hydrocarbons (HCs), which are also sources for syngas. Hence, catalytic steam reforming is an effective technique to address tar formation and improve H production from biomass gasification. Of the various classes in existence, supported metal catalysts are considered the most promising. This paper focuses on the current researching status, prospects, and challenges of steam reforming of gasified biomass tar. Besides, it includes recent developments in tar compositional analysis, supported metal catalysts, along with the reactions and process conditions for catalytic steam reforming. Moreover, it discusses alternatives such as dry and autothermal reforming of tar.

关键词： hydrogen     biomass gasification     tar     steam reforming     catalyst    

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Hydrogen production from co-gasification of coal and biomass in supercritical water by continuous flow

YAN Qiuhui, GUO Liejin, LIANG Xing, ZHANG Ximin

《能源前沿（英文）》 2007年 第1卷 第3期   页码 327-330 doi: 10.1007/s11708-007-0048-0

摘要： Hydrogen is a clean energy carrier. Converting abundant coal sources and green biomass energy into hydrogen effectively and without any pollution promotes environmental protection. The co-gasification performance of coal and a model compound of biomass, carboxymethylcellulose (CMC) in supercritical water (SCW), were investigated experimentally. The influences of temperature, pressure and concentration on hydrogen production from co-gasification of coal and CMC in SCW under the given conditions (20–25 MPa, 650vH, 15–30 s) are discussed in detail. The experimental results show that H, CO and CH are the main gas products, and the molar fraction of hydrogen reaches in excess of 60%. The higher pressure and higher CMC content facilitate hydrogen production; production is decreased remarkably given a longer residence time.

关键词： carboxymethylcellulose     temperature     co-gasification performance     Hydrogen     residence    

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Pilot scale autothermal gasification of coconut shell with CO

Bayu PRABOWO,Herri SUSANTO,Kentaro UMEKI,Mi YAN,Kunio YOSHIKAWA

《能源前沿（英文）》 2015年 第9卷 第3期   页码 362-370 doi: 10.1007/s11708-015-0375-5

摘要： This paper explored the feasibility and benefit of CO utilization as gasifying agent in the autothermal gasification process. The effects of CO injection on reaction temperature and producer gas composition were examined in a pilot scale downdraft gasifier by varying the CO /C ratio from 0.6 to 1.6. O was injected at an equivalence ratio of approximately 0.33–0.38 for supplying heat through partial combustion. The results were also compared with those of air gasification. In general, the increase in CO injection resulted in the shift of combustion zone to the downstream of the gasifier. However, compared with that of air gasification, the long and distributed high temperature zones were obtained in CO -O gasification with a CO /C ratio of 0.6–1.2. The progress of the expected CO to CO conversion can be implied from the relatively insignificant decrease in CO fraction as the CO /C ratio increased. The producer gas heating value of CO -O gasification was consistently higher than that of air gasification. These results show the potential of CO -O gasification for producing high quality producer gas in an efficient manner, and the necessity for more work to deeply imply the observation.

关键词： biomass gasification     CO2     downdraft gasifier     autothermal    

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Modeling and simulation of biomass air-steam gasification in a fluidized bed

KONG Xiaoying, WU Chuangzhi, YUAN Zhenhong, MA Longlong, CHANG Jie, LÜ Pengmei

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 209-213 doi: 10.1007/s11705-008-0039-7

摘要： By considering the features of fluidized-bed reactors and the kinetic mechanism of biomass gasification, a steady-state, isothermal, one-dimensional and two-phase mathematical model of biomass gasification kinetics in bubbling fluidized beds was developed. The model assumes the existence of two phases – a bubble and an emulsion phase – with chemical reactions occurring in both phases. The axial gas dispersion in the two phases is accounted for and the pyrolysis of biomass is taken to be instantaneous. The char and gas species CO, CO, H, HO, CH and 8 chemical reactions are included in the model. The mathematical model belongs to a typical boundary value problem of ordinary differential equations and its solution is obtained by a Matlab program. Utilizing wood powder as the feedstock, the calculated data show satisfactory agreement with experimental results and proves the effectiveness and reliability of the model.

关键词： satisfactory agreement     two-phase mathematical     one-dimensional     pyrolysis     calculated    

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生物质热解气化技术

董玉平,郭飞强,董磊 ,强宁,景元琢

《中国工程科学》 2011年 第13卷 第2期   页码 44-49

摘要：

生物质热解气化是农林废弃物向清洁燃气转化的关键技术，产生的合成气可替代天然气等化石燃料，实现燃气、热能和电能的供给。目前我国生物质热解气化技术经过20余年的发展，完成了民用分布式生物质燃气供应系统的示范和布局，并初步具备了规模化燃气制备和发电的产业技术基础。“十二五”期间，具有显著提高燃气质量的富氧气化、蒸汽气化、甲烷化制备Bio-SNG等技术成为重要的研究方向，装备设计制造的大型化、规范化和标准化成为产业发展的必然。

关键词： 生物质     热解气化     合成气     Bio-SNG    

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Alkali-thermal gasification and hydrogen generation potential of biomass

Alexander B. Koven, Shitang S. Tong, Ramin R. Farnood, Charles Q. Jia

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 369-378 doi: 10.1007/s11705-017-1662-y

摘要： Generating hydrogen gas from biomass is one approach to lowering dependencies on fossil fuels for energy and chemical feedstock, as well as reducing greenhouse gas emissions. Using both equilibrium simulations and batch experiments with NaOH as a model alkaline, this study established the technical feasibility of converting various biomasses (e.g., glucose, cellulose, xylan and lignin) into H -rich gas via catalyst-free, alkali-thermal gasification at moderate temperatures (as low as 300 °C). This process could produce more H with less carbon-containing gases in the product than other comparable methods. It was shown that alkali-thermal gasification follows , with carbonate being the solid product which is different from the one suggested in the literature. Moreover, the concept of hydrogen generation potential (H -GP)—the maximum amount of H that a biomass can yield, was introduced. For a given biomass C H O , the H -GP would be moles of H . It was demonstrated experimentally that the H -GP was achievable by adjusting the amounts of H O and NaOH, temperature and pressure.

关键词： hydrogen generation potential     biomass     lignocellulose     alkali-thermal gasification     sodium hydroxide    

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Experimental research on catalysts and their catalytic mechanism for hydrogen production by gasification

PEI Aixia, GUO Liejin, JIN Hui

《能源前沿（英文）》 2007年 第1卷 第4期   页码 451-456 doi: 10.1007/s11708-007-0066-2

摘要： Peanut shell, mixed with sodium carboxymethylcellulose, was gasified at a temperature of 450°C and a pressure range from 24 to 27 MPa with the presence of different catalysts, including KCO, ZnCl and Raney-Ni. The experimental results show that different catalysts have greatly different effects on the reaction. Gasification efficiency (GE), hydrogen gasification efficiency (GHE), carbon gasification efficiency (GCE), yield of hydrogen production ( ) and potential yield of hydrogen production () are applied to describe the catalytic efficiency. From the result of gaseous components, ZnCl has the highest hydrogen selectivity, KCO is lower, and Raney-Ni is the lowest, but Raney-Ni is the most favorable to gasify biomass among the three catalysts, and its , , reach 126.84%, 185.71%, 94.24%, respectively. As expected, hydrogen selectivity increased and CH reduced rapidly when the mixture of ZnCl and Raney-Ni is used under the same condition. The optimization mixture appeared when 0.2 g of ZnCl was added to 1 g of Raney-Ni, 43.56 g · kg of hydrogen pro duction was obtained. In addition, the catalytic mechanisms of different catalysts were analyzed, and the possible reaction pathway was brought forward, which helped to explain the experiment phenomena and results correctly.

关键词： presence     Raney-Ni     biomass     optimization mixture     possible reaction    

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Dilution sampling and analysis of particulate matter in biomass-derived syngas

Xiaoliang WANG, Curtis ROBBINS, S. Kent HOEKMAN, Judith C. CHOW, John G. WATSON, Dennis SCHUETZLE

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 320-330 doi: 10.1007/s11783-011-0347-x

摘要： Thermochemical biomass gasification, followed by conversion of the produced syngas to fuels and electrical power, is a promising energy alternative. Real-world characterization of particulate matter (PM) and other contaminants in the syngas is important to minimize damage and ensure efficient operation of the engines it powers and the fuels created from it. A dilution sampling system is demonstrated to quantify PM in syngas generated from two gasification plants utilizing different biomass feedstocks: a BioMax 15 Biopower System that uses raw and torrefied woodchips as feedstocks, and an integrated biorefinery (IBR) that uses rice hulls and woodchips as feedstocks. PM mass concentrations in syngas from the IBR downstream of the purification system were 12.8–13.7 μg·m , which were significantly lower than the maximum level for catalyst protection (500 μg·m ) and were 2–3 orders of magnitude lower than those in BioMax 15 syngas (2247–4835 μg·m ). Ultrafine particle number concentration and PM chemical constituents were also much lower in the IBR syngas than in the BioMax 15. The dilution sampling system enabled reliable measurements over a wide range of concentrations: the use of high sensitivity instruments allowed measurement at very low concentrations (~1 μg·m ), while the flexibility of dilution minimized sampling problems that are commonly encountered due to high levels of tars in raw syngas (~1 g·m ).

关键词： dilution source sampling     syngas characterization     biomass gasification     ultrafine particles    

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Experimental evaluation of a 35 kVA downdraft gasifier

Ashok Jayawant Rao KECHE, Gaddale AMBA PRASAD RAO

《能源前沿（英文）》 2013年 第7卷 第3期   页码 300-306 doi: 10.1007/s11708-013-0247-9

摘要： Energy conversion systems based on biomass are particularly interesting because biomass utilization effectively closes the carbon cycle besides achieving self-sustainability. Biomass is particularly useful for highly populated and agriculture dependent economic nations like China and India. A compact and cost effective downdraft gasification system was developed. The present paper describes an experimental investigation on a biomass based gasifier engine system with a capacity of 35 kVA for power generation application. The problem of cooling and cleaning the hot and dirty gas from the gasifier has been satisfactorily solved by the effective cooling and filtration system. The gasifier developed is observed to be operation friendly. The quality of gas was evaluated in terms of its composition, conversion efficiency and total particulate matter. The maximum output of the power plant was obtained at the combustion zone temperature of 850oC. The experimental investigations showed that the percentage reduction in total particulate matter is 89.32%. The conversion efficiency of the biomass gasifier is found to be dependent on the operation conditions and fuel properties of the gasifier. The optimum value of equivalence ratio was observed to be 0.3134 for achieving the maximum gas conversion efficiency of the present gasifier configuration.

关键词： biomass     gasification     producer gas     equivalence ratio     total particulate matter     conversion efficiency of gasifier    

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A steam dried municipal solid waste gasification and melting process

Gang XIAO, Baosheng JIN, Mingjiang NI, Kefa CEN, Yong CHI, Zhongxin TAN

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 193-204 doi: 10.1007/s11783-010-0268-0

摘要： Considering high-moisture municipal solid waste (MSW) of China, a steam dried MSW gasification and melting process was proposed, the feasibility was tested, and the mass and energy balance was analyzed. Preliminary experiments were conducted using a fixed-bed drying apparatus, a 200 kg per day fluidized-bed gasifier, and a swirl melting furnace. Moisture percentage was reduced from 50% to 20% roughly when MSW was dried by slightly superheated steam of 150°C–350°C within 40 min. When the temperature was less than 250°C, no incondensable gas was produced during the drying process. The gasifier ran at 550°C–700°Cwith an air equivalence ratio (ER) of 0.2–0.4. The temperature of the swirl melting furnace reached about 1240°C when the gasification ER was 0.3 and the total ER was 1.1. At these conditions, the fly ash concentration in the flue gas was 1.7 g·(Nm ) , which meant over 95% fly ash was trapped in the furnace and discharged as slag. 85% of Ni and Cr were bound in the slag, as well as 60% of Cu. The mass and energy balance analysis indicates that the boiler heat efficiency of an industrial MSW incineration plant reaches 86.97% when MSW is dried by steam of 200°C. The boiler heat efficiency is sensitive to three important parameters, including the temperature of preheated MSW, the moisture percentage of dried MSW and the fly ash percentage in the total ash.

关键词： municipal solid waste (MSW)     steam drying     gasification and melting    

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Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

《环境科学与工程前沿（英文）》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1096-5

摘要：

PE ball milling pretreatment induces higher H2 production and purity by gasification.

Ca(OH)2 reacts at solid state with PE boosting H2 and capturing CO2.

Ca(OH)2 significantly reduces methanation side-reaction.

关键词： Hydrogen production     Gasification     Plastic waste     High energy ball milling    

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Crystallization and viscosity-temperature characteristics during co-gasification of industrial sludge

Linmin ZHANG, Bin LIU, Juntao WEI, Xudong SONG, Yonghui BAI, Jiaofei WANG, Ying ZHOU, Huijun YANG, Guangsuo YU

《能源前沿（英文）》 2022年 第16卷 第6期   页码 1037-1047 doi: 10.1007/s11708-022-0824-x

摘要： Co-gasification of industrial sludge (IS) and coal was an effective approach to achieve harmless and sustainable utilization of IS. The long-term and stable operation of a co-gasification largely depends on fluidity of coal-ash slag. Herein, the effects of IS addition on the crystallization and viscosity of Shuangmazao (SMZ) coal were investigated by means of high temperature stage coupled with an optical microscope (HTSOM), a scanning electron microscopy coupled with an energy dispersive X-ray spectrometry (SEM-EDS), X-ray diffraction (XRD), a Fourier transform infrared spectrometer (FTIR), and FactSage software. The results showed that when the proportion of IS was less than 60%, with the addition of IS, the slag existed in an amorphous form. This was due to the high content of SiO2 and Al2O3 in SMZ ash and blended ash, which had a high glass-forming ability (GFA). The slag formed at a high temperature had a higher polymerization degree and viscosity, which led to a decrease in the migration ability between ions, and ultimately made the slag difficult to crystallize during the cooling. When the proportion of IS was higher than 60%, the addition of IS increased the CaO and FeO content in the system. As network modifiers, CaO and FeO could provide O2− at a high temperature, which reacted with silicate network structure and continuously destroyed the complexity of network structure, thus reducing the polymerization degree and viscosity of slag. At this time, the migration ability between ions was enhanced, and needle-shaped/rod-shaped crystals were precipitated during the cooling process. Finally, the viscosity calculated by simulation and Einstein-Roscoe empirical formula demonstrated that the addition of IS could significantly improve the fluidity of coal ash and meet the requirements of the liquid slag-tapping gasifier. The purpose of this work was to provide theoretical support for slag flow mechanisms during the gasifier slagging-tapping process and the resource treatment of industrial solid waste.

关键词： co-gasification     industrial sludge     crystallization     viscosity     mineral matter evolution    

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标题 作者 时间 类型 操作

NUMERICAL MODELING OF BIOMASS GASIFICATION USING COW DUNG AS FEEDSTOCK

期刊论文

Hydrogen production by biomass gasification in supercritical or subcritical water with Raney-Ni and other

Aixia PEI, Lisheng ZHANG, Bizheng JIANG, Liejin GUO, Ximin ZHANG, Youjun LV, Hui JIN,

期刊论文

Biomass to dimethyl ether by gasification/synthesis technology

Tiejun WANG, Yuping LI, Longlong MA, Chuangzhi WU

期刊论文

Catalytic steam reforming of tar for enhancing hydrogen production from biomass gasification: a review

Ru Shien TAN, Tuan Amran TUAN ABDULLAH, Anwar JOHARI, Khairuddin MD ISA

期刊论文

Hydrogen production from co-gasification of coal and biomass in supercritical water by continuous flow

YAN Qiuhui, GUO Liejin, LIANG Xing, ZHANG Ximin

期刊论文

Pilot scale autothermal gasification of coconut shell with CO

Bayu PRABOWO,Herri SUSANTO,Kentaro UMEKI,Mi YAN,Kunio YOSHIKAWA

期刊论文

Modeling and simulation of biomass air-steam gasification in a fluidized bed

KONG Xiaoying, WU Chuangzhi, YUAN Zhenhong, MA Longlong, CHANG Jie, LÜ Pengmei

期刊论文

生物质热解气化技术

董玉平,郭飞强,董磊 ,强宁,景元琢

期刊论文

Alkali-thermal gasification and hydrogen generation potential of biomass

Alexander B. Koven, Shitang S. Tong, Ramin R. Farnood, Charles Q. Jia

期刊论文

Experimental research on catalysts and their catalytic mechanism for hydrogen production by gasification

PEI Aixia, GUO Liejin, JIN Hui

期刊论文

Dilution sampling and analysis of particulate matter in biomass-derived syngas

Xiaoliang WANG, Curtis ROBBINS, S. Kent HOEKMAN, Judith C. CHOW, John G. WATSON, Dennis SCHUETZLE

期刊论文

Experimental evaluation of a 35 kVA downdraft gasifier

Ashok Jayawant Rao KECHE, Gaddale AMBA PRASAD RAO

期刊论文

A steam dried municipal solid waste gasification and melting process

Gang XIAO, Baosheng JIN, Mingjiang NI, Kefa CEN, Yong CHI, Zhongxin TAN

期刊论文

Augmented hydrogen production by gasification of ball milled polyethylene with Ca(OH)

Giovanni Cagnetta, Kunlun Zhang, Qiwu Zhang, Jun Huang, Gang Yu

期刊论文

Crystallization and viscosity-temperature characteristics during co-gasification of industrial sludge

Linmin ZHANG, Bin LIU, Juntao WEI, Xudong SONG, Yonghui BAI, Jiaofei WANG, Ying ZHOU, Huijun YANG, Guangsuo YU

期刊论文